Here’s the thing: our blinds ARE always closed, we just flip them (not raise up, but turn) during daytime to have lights in and flip back for the night. but they are always down.
Understood, but still comes down to allowing warmer room air access to the windows at night, so you can either raise the closed blinds a few inches or else leave them open all night.
A bit more on using a gauge to measure the Rh and how it relates to window condensation....
Dew point is defined as saturation vapor density, or 100% relative humidity, or as the transition temperature between evaporation and condensation. Dew point temperature is based on the amount of water in the air and is unaffected by air temperature. If you are so inclined the dew point temperature can be found by comparing air temperature to relative humidity on an appropriate chart. You can also do the math of course, but use the chart, trust me on that.
Condensation occurs on windows because the glass temperature is below the dew point temperature of the air. That's it, nothing magic about it. If the window temperature is below the dew point you have condensation, if window temp is above the dew point you don't. That's why you don't want to block warmer room air from the window at night.
In order to control condensation from forming on the surface of a window you either:
(a) lower the dew point to a level below the temperature of the window surface
(b) warm up the window surface to a temperature above the dew point
(c) do both
Consider a home at 65°F with a measured relative humidity reading of 40%. In this scenario there is 6.25 grams of water per cubic meter of air in the home equating to a dew point of 38°F. If the window glass temperature goes below the dew point then it's pretty much a certainty that there will be condensation and maybe even ice formation on the window.
Since (apparently) in this scenario the Rh is too high, we can raise the air temp to 75°F and lower the Rh to 29% which is (apparently) well within the recommended range of Rh to avoid window condensation. So now all is good, right?
Well not so much because lowering the Rh by raising the room temperature did nothing to lower the level of water in the air, it remains 6.25 grams per cubic meter and the dew point is still 38°. So despite measuring 29% on the fancy new Rh gauge, you still have condensation on your windows. So much for using the new gauge.
Your home was built in 2000 and by that time a high percentage of windows were being manufactured with LowE coating and argon, but we don't know if yours were or not. Hopefully they were because that will be a definite factor on how you can control condensation. And since once you open the blinds in the morning the east-facing windows (sunrise) appear to have less condensation than the west-facing windows (shadow), I suspect that your windows might be okay.
Once again leave the blinds open at night and see what happens. Forget "air leakage" at the edge, internal storms, plastic, and so on for the moment, you first need to find out what the closed blinds are doing. Leaving the blinds open will help, but might not be a 100% fix, but at least you will now have a place to start.