I have smelled phosgene from the old days when we used halide leak torches and yes I did refrigeration/R12 work. When this bugger blew my customer was nearby and it smelled like acid/phosgene and I was in no mood to analyze it. Sure glad I never went thru WW1 like my Grandpa did. They used mustard gas/chlorine/phosgene and any other nasty chemical they could find on each other.