The vent holes should vary dependent of it's location in relation to the boiler. Small holes closer to the boiler and get larger further away. This way all the radiators heat up at the same time.
To check if the vent is working on the attic radiator, remove it, and see if it heats up. You will need to stay by the radiator and be ready to use the shutoff when steam starts pushing out the vent hole.
If you replace the vent, get the largest vent size you can, so the radiator will heat up properly.
You can look up, "Balancing a steam radiator system" to understand, in detail, why the size variances exist.
Ron - Good explanation.
Thinking more, in a steam system these vents are functioning devices (i.e. moving parts). For small steam systems, the thermostat cycles the boiler from a centrally located thermostat. The system fills with steam which displaces the air in the radiators. The vents release air at the radiators until filled with steam. I recall the vents use the heat in steam to expand a heat sensitive device and close. For one pipe, the steam condenses in the radiators and by gravity the condensate travels back through the single pipe to the boiler. The single pipe is sized to both carry the steam and condensate in the opposite direction. When the thermostat is satisfied, the boiler cycles off and as the remaining steam condenses, a vacuum is created that pulls air back into the radiators through the vent via an integral vacuum break or other means. The process then repeats itself. This explanation is text book without any knowledge of your system.
A small advancement is the integration of a thermostat with the vent. This vents the air until the room temperature is satisfied. Even with this, the entire system must cycle to maintain comfort.
In a very large turn of century single pipe system I worked with three decades ago, the inlet valve to the radiator was a pneumatic two position control valve that a local thermostat completely opened and closed. The valves originally had leather pneumatic bellows and the building mechanic could still get parts.
The valves upstream of the radiator only provide shut-off, not control.
Again like most have indicated, appears your difficulty is at the radiator.