Yes you can use that vent assuming that was being used as the previous way to vent the bathroom but you need to vent it directly to the exterior, you dont want moist air building up in the attic, and yes you could get away with changing that device to a two gang ring IF it was installed with a 4x4 junction box AND that circuit is dedicated to the bathroom, with the bathroom fan using less than 50% of the circuit ampere rating....HOWEVER, a bathroom fan and blow dryer may not last long on a 15 Amp Circuit, which is probably why 08 code requires 20 amp circuits in bathrooms...