The simplest way to hook it up would probably be to plumb your cold water feed into one end, and plumb the other end of the wood furnace DHW coil to feed your electric heater. That way if the furnace is hot, the water will be pre-heated when it goes into the electric, and less energy or no energy will be used to heat that water. If the furnace is off the electric water heater will work just as it does now, getting it's cold supply through the wood furnace.
There are probably fancier ways to do it with circulator pumps and thermostats, etc, but I'll leave that mumbo jumbo to the plumbers.