SourMash:
People often assume that the most common cause of bad solder joints is water in the piping or not enough heat, but that's not true.
The most common cause of bad solder joints is that they don't leave an escape route for the air or steam pressure in the piping to escape. When you heat the piping to solder it, then you get both thermal expansion of the air and/or steam generation. If you don't provide a path for the increasing pressure inside the piping to escape OTHER THAN the joint you're trying to solder, then the pressure building up inside the piping will push the hot flux out of the joint, allowing air into that joint.
Soldering flux is nothing more than Petroleum Jelly (sold as "Vaseline") with an acid (or a chemical called zinc chloride added to it to make it acidic at soldering temperatures), and hot Petroleum Jelly will burn if exposed to the torch flame. So, you have a situation where the solder flux gets pushed out of the joint and what's left behind might burn away and expose the bare copper metal to oxygen in the air whereby it will form an oxide film on the copper metal almost instantanesously. Copper oxide is brown in colour, and it's the reason why new pennies and copper pipes are orange and old pennies and copper pipes are brown. That oxide film is slow to form at room temperature, but forms extremely quickly at soldering temperatures. In fact, the reason why soldering flux has the acid or zinc chloride in it is to dissolve the copper oxide inside the joint to expose bare copper. Copper oxide dissolves much more readily in hot acid than the copper metal itself.
WHEREAS, if you supply an alternate path for the pressure inside the pipe to escape, then capillary pressure holds the molten flux inside the joint until the solder starts to melt and the greater affinity of the molten solder to the copper (and hence higher capillary pressure of the molten solder) pushes that molten flux out of the joint. That flux being inside the joint prevents oxygen in the air from contacting the bare copper metal to ensure there is no copper oxide present inside the joint.
PS: You CAN use ordinary Vaseline as soldering flux. It doesn't work well, but it does work. You just have to "Vaseline" the joints immediately after sanding or brushing them to prevent any oxide film from forming on the bare copper metal until you solder the joint.
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Last edited by Nestor_Kelebay; 12-16-2008 at 06:30 PM.
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