painting metal doors
A primer and a nice interior/exterior "Metal & Wood" enamel would work
For example, I like Ben Moore's M&W
The low lustre is self-priming, so a coat of low lustre, then a coat or two of high gloss would do just fine
Other than that, you could prime both sides (I'm assuming these are exterior doors), and use in interior enamel inside, and an exterior (trim) paint outside
In this case I would use BM's Waterborne Impervo inside, and BM's Moorglo Soft Gloss outside
As they are bare and I'm guessing rust isn't an issue, acrylic or alkyd, your choice
Alkyds (oils) tend to be better rust inhibitors
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