painting a basement ...??
Before painting any masonry surface you should check for moisture, take a piece of plastic about a foot square and tape it onto the center of each wall with duct tape, sealing up all four sides of it well, leave it there for about 24 hours then remove it. If the inside of the plastic is dry you have no moisture issue, if there is moisture, water, condensation on the plastic then you have a moisture issue which you should fix first. When painting concrete block that has never been painted you want to use a block filler, that will fill the pin holes and make the block not so porous, I would use Sherwin Williams block filler followed by two coats of a quality 100% acrylic latex in your choice of sheens.
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